Search results for "Brine disposal"

A continuous plug flow reactor for magnesium recovery from concentrated brine

2015

Magnesium is one of the eight most abundant elements on the world and the third most abun- dant in the sea, buc practically only two countries (Russia and China) control the world market for this compound. Product purity, Mg recovery, crystal morphology and granulometric distribution of precipitated particles were examined through careful laboratory analysis and results from different tests were compared, in order to identify the effect of allcaline species’ nature and concentration on precipitation phenomena.

Magnesium recovery from concentrated brines

2014

Reactive crystallisation process for magnesium recovery from concentrated brines

2014

Seawater brines, generated either by natural or anthropic processes, often cause significant environmental issues related to their disposal. A clear example is the case of brines from desalination plants, which can have severe environmental impacts on the receiving water body. On the other side, brines can represent a rich and appealing source of raw materials, especially when they are very concentrated, as it happens with bitterns (i.e. exhausted brines) produced in saltworks. In particular, magnesium concentration can reach values up to 30-40 kg/m3 of brine, which is 20-30 times that of typical seawater. An experimental campaign has been carried out in the present work for assessing the p…

Modelling and bench scale investigation of inclined dense jets

2002

Advanced energetics of a Multiple Effects Evaporation (MEE) desalination plant Part I: 2nd principle analysis by a zooming representation at single-e…

2010

This paper represents the Part I of a paper in two parts, aimed at proposing a 2nd principle and thermoeconomic analysis for a Multiple Effects Evaporation (MEE) process and discussing solutions for optimization and energy saving. After a brief analysis of the thermochemical fundamentals of desalination, the minimum theoretical work of separation is introduced to represent a reference condition for the assessment of plants' efficiency. A forward feed MEE configuration is then analysed, abandoning the conventional approach to “at overall plant-level”-analysis; a zooming strategy, based on focusing on the physical model of a generic stage (i.e. effect), is preferred to best recognize the marg…

A brine evaporative cooler/concentrator for autonomous thermal desalination units

2011

In recent years growing attention has been paid to the problem of brine disposal due to the raising awareness of significant environmental issues related to the use of desalination processes for fresh water production. This is particularly relevant when desalination units are located in remote sites, characterised by major complexity in the construction and management of intake and outfall structures. In the present work a novel device, named brine evaporative cooler/concentrator (BECC, patent pending), has been developed for coupling with small-scale thermal desalination plants in order to reduce the problem of brine disposal. Such device fulfils two different functions: i) cooling of the …

Valorization of surface-water RO brines via Assisted-Reverse Electrodialysis for minerals recovery: Performance analysis and scale-up perspectives

2022

Reverse osmosis (RO) processes have been recently identified as mostly capable of quantitative removal of salts and contaminants from saline and surface waters, though posing the problem of a concentrated brine to be disposed of and a produced permeate too low in minerals, thus requiring a sometimes expensive remineralization step. In the present paper, Assisted-Reverse Electrodialysis (A-RED) has been proposed for the remineralization of surface-water RO permeate by recovering minerals from its brine. A purposely developed and validated model has been adopted to carry out a parametric analysis for design and optimization of an industrial-scale plant. The techno-economic analysis underlined…

Magnesium recovery from exhausted brine

2015

Mg and MgCO3 are among the 20 EU critical raw materials. Interestingly, Mg can be found at very high concentration in brines generated as waste stream from salt works. Literature works have demonstrated the feasibility of Mg extraction from brines [1–3] by reactive precipitation, for the production of Mg(OH)2. Here we present an overview of the experimental campaigns carried out using exhausted brine from real salt works (Italy) to produce Mg(OH)2 with high purity and conversion. Lab – and pilot-scale batch and semi-continuous CSTR crystallisers were developed and tested, eventually leading to a continuous process by a quasi-PFR pilot reactor. Different alkaline solutions have been adopted …